Properties of silver bromide vapors.

Details

• Personal Author:
  Marek BC ; Visnapuu, Aarne
• Description:
  Knudsen cell mass spectrometric analysis of the vapors over molten AgBr between 711 deg and 963 deg K indicates the existence of three vapor molecules: AgBr, Ag3Br2, and Ag3Br3. "Second law" heats of vaporization, delta-hv1 for the three vapor species are calculated to be 41.4+/-1.1 Kcal mole-1, 33.6+/-1.1 Kcal mole1, and 29.2+/-1.8 Kcal mole-1, respectively. The heat of trimerization is --95.0+/-3.8 Kcal mole-1. Ionization potentials for AgBr, Ag3Br2, and Ag3Br3 are 9.5+/-0.3 eV, 10.0+/-0.2 eV, and 9.8+/-0.2 eV respectively. [Description provided by NIOSH]
• Subjects:
  Metals Occupational Health Safety Silver
• Keywords:
  Metals; Metallurgical-processes; Metallurgy; Silver-compounds
• Series:
  Mining Publications
• ISSN:
  0022-5088
• Document Type:
  Text
• Genre:
  Journal Article
• Place as Subject:
  Missouri ; OSHA Region 7
• CIO:
  National Institute for Occupational Safety and Health (NIOSH)
• Division:
  RORC - Rolla Research Center
• Topic:
  Workplace Safety & Health
• Location:
  North America
• Pages in Document:
  89-96
• Volume:
  25
• Issue:
  1
• NIOSHTIC Number:
  nn:10010207
• Citation:
  J Less-Common Met 1971 Sep; 25(1):89-96
• Federal Fiscal Year:
  1971
• Peer Reviewed:
  True
• Source Full Name:
  Journal of the Less-Common Metals
• Collection(s):
  National Institute for Occupational Safety and Health
• Main Document Checksum:
  urn:sha-512:7dc847c09aedf140bc731323e8446b4703641ae07d6ad9e7b7238120dab30b8f7dcaa9b938d34d035f87873a0fe7fec262d5d13dcaf290925445e82b6de3b57d
• Download URL:
  https://stacks.cdc.gov/view/cdc/246829/cdc_246829_DS1.pdf
• File Type:
  [PDF - 168.02 KB ]