Development of a quantitative air sampling and analytical method for diethylcarbamoyl chloride.

Details

• Personal Author:
  Glaser, Robert A.
• Description:
  An air sampling and analytical determination method for the detection of diethylcarbamoyl chloride (88108) (DECC) is described. The method involves collection of the analyte on Porapak P, a styrene-divinylbenzene porous polymer. The samples are desorbed with ethyl acetate and the resulting solution is analyzed by gas chromatography using a flame ionization detector. No significant effects upon DECC recovery were observed when a solution containing both contaminants, dimethylamine and aniline, was analyzed. Benzylamine exerted a negative effect upon DECC recovery that correlated with increases in storage time, temperature, and the amount of amine spiked. The recoveries of the refrigerated samples stored for 7, 14, or 28 days did not differ significantly from those stored for 1 day. The method was validated over the range of 40 to 1250 micrograms DECC per sample. [Description provided by NIOSH]
• Content Notes:
  in NTRL, no PDF
• Subjects:
  Carcinogens Environmental Exposure Environmental Monitoring Mutagens Occupational Exposure Occupational Health Safety
• Keywords:
  NIOSH-Publication; Analytical-methods; Air-sampling; Quantitative-analysis; Chemical-carcinogens; Mutagenic-effects; Chemical-exposure; Personal-air-sampling; Personal-exposure-detectors; Sampling-methods
• Document Type:
  Text
• Genre:
  Report
• Place as Subject:
  Ohio ; OSHA Region 5
• CIO:
  National Institute for Occupational Safety and Health (NIOSH)
• Division:
  DPSE - Division of Physical Sciences and Engineering
• Topic:
  Workplace Safety & Health
• Location:
  North America
• Pages in Document:
  1-21
• NIOSHTIC Number:
  nn:00095018
• NTIS Accession Number:
  PB80195332
• Citation:
  NIOSH 1980 Mar; :1-21
• CAS Registry Number:
  Diethylcarbamoyl chloride (CAS RN 88-10-8)
• Federal Fiscal Year:
  1980
• Peer Reviewed:
  False
• Source Full Name:
  Division of Physical Sciences and Engineering, NIOSH, Cincinnati, Ohio, 21 pages, 8 references
• Collection(s):
  National Institute for Occupational Safety and Health
• Main Document Checksum:
  urn:sha-512:7dc847c09aedf140bc731323e8446b4703641ae07d6ad9e7b7238120dab30b8f7dcaa9b938d34d035f87873a0fe7fec262d5d13dcaf290925445e82b6de3b57d
• Download URL:
  https://stacks.cdc.gov/view/cdc/241082/cdc_241082_DS1.pdf
• File Type:
  [PDF - 168.02 KB ]