Some Mass Spectral and Analytical Aspects of Deuterium Labeling of Straight-Chain Olefins

Details

• Personal Author:
  Decora AW ; Doolittle FG ; Earnshaw DG
• Description:
  A calculation method has been developed to enhance the effect of deuterium labeling in the mass spectra of linear vicinal dideuterioalkanes (lvda). Individual lvda can be identified from these enhanced spectra. Single carbon-number mixtures of lvd nonanes and lvd decanes have been analyzed successfully using matrices derived from spectra of standards. In addition, enhanced mass spectra have been predicted for all of the lvd heptadecanes and lvd nonadecanes. Matrices have been constructed from the predicted spectra, and preliminary tests of these matrices have been conducted. All identifications and analytical results on the lvda studied can be used to identify the precursor olefins. [Description provided by NIOSH]
• Subjects:
  Alkanes Hydrocarbons Mass Spectrometry Occupational Health Safety Spectrum Analysis
• Keywords:
  Mass-spectrometry Spectrographic-analysis
• Series:
  Mining Publications
• ISSN:
  0030-493X
• Document Type:
  Text
• Genre:
  Journal Article
• Place as Subject:
  OSHA Region 8 ; Wyoming
• CIO:
  National Institute for Occupational Safety and Health (NIOSH)
• Division:
  LERC - Laramie Energy Research Center
• Topic:
  Workplace Safety & Health
• Location:
  North America
• Volume:
  5
• Issue:
  7
• NIOSHTIC Number:
  nn:10010215
• Citation:
  Org Mass Spectrom 1971 Jul; 5(7):801-815
• Federal Fiscal Year:
  1971
• Peer Reviewed:
  True
• Source Full Name:
  OMS. Organic Mass Spectrometry
• Collection(s):
  National Institute for Occupational Safety and Health
• Main Document Checksum:
  urn:sha-512:68c9bd1ff8b38520bf3e20e696b25ca83cbf9a680db238b14a8403fa1da04200a03c9fea5f0f85d181a88de0c83c22687f0900bcb378bf83f835e1989f7bd8a8
• Download URL:
  https://stacks.cdc.gov/view/cdc/219975/cdc_219975_DS1.pdf
• File Type:
  [PDF - 952.68 KB ]