NIOSH Manual of Analytical Methods (NMAM), 5th Edition [print edition]

Details

• Alternative Title:
  NIOSH Manual of Analytical Methods (NMAM), 5th Edition
• Personal Author:
  Abell, Martin T. ; Agrawal, Anoop ; Andrews, Ronnee N. ; Arnold, James E. ; Ashley, Kevin E. ; Baron, Paul A. ; Bartley, David L. ; B'Hymer, Clayton ; Birch, M. Eileen ; Birch, Quinn T. ; Blanchere, Francoise M. ; Boiano, James M. ; Boraiko, C. ; Breuer, Dietmar ; Cassinelli, Mary E. ; Dollberg, Donald D. ; Downs, Corey C. ; Dozier, Alan K. ; Eisenhardt, Anna ; Eller, Peter M.
• Corporate Authors:
  National Institute for Occupational Safety and Health
• Description:
  The National Institute for Occupational Safety and Health (NIOSH) is the U.S. federal agency responsible for conducting research and making recommendations for the prevention of work-related injury and illness. NIOSH is part of the Centers for Disease Control and Prevention (CDC) in the U.S. Department of Health and Human Services. The NIOSH Manual of Analytical Methods (NMAM) is a compilation of validated sampling and analytical methods that are used globally for occupational exposure assessment in the industrial (occupational) hygiene field and related professions. The methods that are published in NMAM are evaluated and validated in consideration of their fitness-for-purpose for exposure monitoring in work areas. NIOSH methods primarily address workplace air sampling and analysis, but NMAM also includes protocols for biological, surface, dermal, and bulk samples. Within NMAM, but separate from the methods themselves, are assorted chapters providing background and guidance covering a number of subjects. Explanatory chapters on quality assurance, sampling guidance, method development and evaluation, aerosol collection, etc., provide valuable information to users of NIOSH methods. NMAM chapters provide a convenient resource that augments technical information often (but not always) available elsewhere in texts and monographs. Now in its fifth edition, NMAM is continuously updated as new or revised methods are evaluated and their performance verified. This document is a compilation of its guidance chapters and methods, current as of the date shown on the front page. NMAM is published online at https://www.cdc.gov/niosh/nmam/ and is available worldwide free of charge. Users are encouraged to visit the NMAM 5th edition website for the most current methods and guidance chapters.
  
  The 72 Methods included are: 501: Particulates N.O.R., Total
  
  1453: Vinyl Acetate
  
  2005: Nitroaromatic Compounds
  
  2008: Chloroacetic Acid
  
  2014: P-Chlorophenol
  
  2016: Formaldehyde
  
  2027: Ketones
  
  2514: Anisidine
  
  2520: Methyl Bromide
  
  2531: Glutaraldehyde
  
  2536: Valeraldehyde
  
  3800: Organic & Inorganic Gases by Extractive FTIR Spectrometry
  
  3900: Volatile Organic Compounds, C1 to C10, Canister Method
  
  5004: Hydroquinone
  
  5005: Thiram
  
  5007: Rotenone
  
  5008: Pyrethrum
  
  5009: Benzoyl Peroxide
  
  5016: Strychnine
  
  5022: Arsenic, Organo-
  
  5033: P-Nitroaniline
  
  5040: Diesel Particulate Matter (as Elemental Carbon)
  
  5100: Carbon Black
  
  5504: Organotin Compounds (as Sn)
  
  5509: Benzidine and 3,3′-Dichlorobenzidine
  
  5524: Metalworking Fluids (MWF) All Categories
  
  5526: Methyltin Chlorides
  
  5528: Polynuclear Aromatic Hydrocarbons in Air by GC-MS Sim
  
  5600: Organophosphorus Pesticides
  
  5601: Organonitrogen Pesticides
  
  5700: Formaldehyde on Dust (Textile or Wood)
  
  6001: Arsine
  
  6002: Phosphine
  
  6010: Hydrogen Cyanide
  
  6012: Sulfuryl Fluoride
  
  6016: Ammonia by IC
  
  6604: Carbon Monoxide
  
  7082: Lead by Flame AAS
  
  7302: Elements by ICP (Microwave Digestion)
  
  7304: Elements by ICP Microwave Digestion
  
  7306: Elements by Cellulosic Internal Capsule Sampler
  
  7400: Asbestos and Other Fibers by PCM
  
  7402: Asbestos by TEM
  
  7405: Alkali Metal Cations Na+, K+, Li+
  
  7502: Zinc Oxide
  
  7600: Chromium, Hexavalent
  
  7602: Silica, Respirable Crystalline, by IR (KBr Pellet)
  
  7603: Quartz in Respirable Coal Mine Dust, by IR (Redeposition)
  
  7605: Chromium, Hexavalent by Ion Chromatography
  
  7701: Lead by Portable Ultrasonic Extraction/ASV
  
  7703: Chromium, Hexavalent by Field-Portable Spectrophotometry
  
  7704: Beryllium in Air by Fluorometry
  
  7906: Particulate Fluorides and Hydrofluoric Acid by Ion Chromatography
  
  7907: Volatile Acids by Ion Chromatography
  
  7908: Non-Volatile Acids (Sulfuric Acid and Phosphoric Acid – Previous Issue)
  
  8007: Toluene in Blood
  
  8200: Elements in Tissues
  
  8308: Fluoride in Urine
  
  8318: 2,5-Hexanedione in Urine
  
  8319: Acetone and Methyl Ethyl Ketone in Urine
  
  8320: Butyltin Trichloride in Urine
  
  8321: O-Cresol in Urine
  
  8322: Trichloroacetic Acid in Urine
  
  8324: 3-Bromopropionic Acid in Urine
  
  8326: S-Benzylmercapturic Acid and S-Phenylmercapturic Acid in Urine
  
  8327: Cyclophosphamide, 4-Ketocyclophosphamide and Ifosfamide in Urine
  
  9000: Asbestos, Chrysotile by XRD
  
  9106: Methamphetamine and Illicit Drugs, Precursors and Adulterants on Wipes by Liquid-Liquid Extraction
  
  9109: Methamphetamine and Illicit Drugs, Precursors and Adulterants on Wipes by Solid-Phase Extraction
  
  9110: Beryllium in Surface Wipes by Fluorometry
  
  9111: Methamphetamine on Wipes by LC/MS
  
  and, 9212: Mitomycin C.
  
  
• Content Notes:
  Stacks staff added the 4 Methods missing from the NIOSH webbook on 2025-02-12. The 3 earlier versions of the 5th Edition Webbook are included in the Supporting Files section for reference and complete representation.
• Subjects:
  Aerosols Chemistry, Analytic Environmental Monitoring Occupational Exposure Occupational Health Safety Urine
• Keywords:
  Air Sampling Techniques Analytical Chemistry Exposure Assessment Industrial Hygiene NIOSH Manual Of Analytical Methods NMAM Occupational Exposure Sampling Methods
• Publisher:
  National Institute for Occupational Safety and Health
• Document Type:
  Text
• Name as Subject:
  NIOSH Manual of Analytical Methods (NMAM)
• Genre:
  Methods
• CIO:
  National Institute for Occupational Safety and Health (NIOSH)
• Division:
  DFSE - Division of Field Studies and Engineering
• Topic:
  Workplace Safety & Health
• Location:
  North America
• Pages in Document:
  980 pdf pages
• Contributor:
  Barton, Giles ; Barton, Nancy ; Collins, Seleen ; Schwegler-Berry, Diane ; Shoemaker, D.A. ; Turkevich, Leonid
• NIOSHTIC Number:
  nn:20069901
• Citation:
  Andrews R, O'Connor PF, eds. Cincinnati, OH: U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health, 2020 Feb ; :1-935
• CAS Registry Number:
  (-)-Amphetamine (CAS RN 156-34-3) ; (-)-Ephedrine hydrochloride (CAS RN 50-98-6) ; (-)-Ephedrine sulfate (CAS RN 134-72-5) ; (-)-Methamphetamine (CAS RN 33817-09-3) ; (-)-Phenylpropanolamine (CAS RN 492-41-1) ; (-)-Pseudoephedrine (CAS RN 321-97-1) ; (+)-Ephedrine (CAS RN 321-98-2) ; (+)-Ephedrine hydrochloride (CAS RN 24221-86-1) ; (+)-Limonene (CAS RN 5989-27-5) ; (+)-Methamphetamine hydrochloride (CAS RN 51-57-0) ; (+)-Phenylpropanolamine (CAS RN 37577-28-9) ; (±)-Amphetamine sulfate (CAS RN 60-13-9) ; (±)-Methamphetamine (CAS RN 7632-10-2) ; (±)-Phenylpropanolamine (CAS RN 14838-15-4) ; (±)-α-Pinene (CAS RN 80-56-8) ; 1-Chloro-4-nitrobenzene (CAS RN 100-00-5) ; 2,3-Hexanedione (CAS RN 3848-24-6) ; 2,3-Pentanedione (CAS RN 600-14-6) ; 2,5-Hexanedione (CAS RN 110-13-4) ; 2-Hexanone (CAS RN 591-78-6) ; 2-Methoxyaniline (CAS RN 90-04-0) ; 2-Nitrotoluene (CAS RN 88-72-2) ; 2-Propenoic acid, 2-methyl-, methyl ester (CAS RN 80-62-6) ; 3,3'-Dichlorobenzidine (CAS RN 91-94-1) ; 3,4-Methylenedioxymethamphetamine (CAS RN 42542-10-9) ; 3,4-Methylenedioxymethamphetamine hydrochloride (CAS RN 64057-70-1) ; 3-Bromopropionic acid (CAS RN 590-92-1) ; 3-Nitrotoluene (CAS RN 99-08-1) ; 4,4'-Diaminodiphenyl (CAS RN 92-87-5) ; 4-Chlorophenol (CAS RN 106-48-9) ; 4-Ketocyclophosphamide (CAS RN 27046-19-1) ; 4-Methoxyaniline (CAS RN 104-94-9) ; 4-Nitroaniline (CAS RN 100-01-6) ; 4-Nitrotoluene (CAS RN 99-99-0) ; Acenaphthene (CAS RN 83-32-9) ; Acenaphthylene (CAS RN 208-96-8) ; Acetic acid, 2,2′-[(dibutylstannylene)bis(thio)]bis-, 1,1′-diisooctyl ester (CAS RN 25168-24-5) ; Acetone (CAS RN 67-64-1) ; Actinolite asbestos (CAS RN 77536-66-4) ; Aldicarb (CAS RN 116-06-3) ; Aluminum (CAS RN 7429-90-5) ; Ammonia (CAS RN 7664-41-7) ; Amosite asbestos (CAS RN 12172-73-5) ; Amphetamine (CAS RN 300-62-9) ; Anthophyllite asbestos (CAS RN 77536-67-5) ; Anthracene (CAS RN 120-12-7) ; Antimony (CAS RN 7440-36-0) ; Arsanilic acid (CAS RN 98-50-0) ; Arsenic (CAS RN 7440-38-2) ; Arsine (CAS RN 7784-42-1) ; Asbestos (CAS RN 1332-21-4) ; Azinphos-methyl (CAS RN 86-50-0) ; Barium (CAS RN 7440-39-3) ; Benomyl (CAS RN 17804-35-2) ; Benz[e]acephenanthrylene (CAS RN 205-99-2) ; Benzanthracene (CAS RN 56-55-3) ; Benzene (CAS RN 71-43-2) ; Benzo[a]pyrene (CAS RN 50-32-8) ; Benzo[ghi]perylene (CAS RN 191-24-2) ; Benzo[k]fluoranthene (CAS RN 207-08-9) ; Benzoyl peroxide (CAS RN 94-36-0) ; Benzylmercapturic acid (CAS RN 19542-77-9) ; Beryllium (CAS RN 7440-41-7) ; Boron (CAS RN 7440-42-8) ; Bromine (CAS RN 7726-95-6) ; Butanedione (CAS RN 431-03-8) ; Butyltin trichloride (CAS RN 1118-46-3) ; Cadmium (CAS RN 7440-43-9) ; Caffeine (CAS RN 58-08-2) ; Calcium (CAS RN 7440-70-2) ; Captan (CAS RN 133-06-2) ; Carbaryl (CAS RN 63-25-2) ; Carbendazim (CAS RN 10605-21-7) ; Carbofuran (CAS RN 1563-66-2) ; Carbon (CAS RN 7440-44-0) ; Carbon black (CAS RN 1333-86-4) ; Carbon disulfide (CAS RN 75-15-0) ; Carbon monoxide (CAS RN 630-08-0) ; Cathine (CAS RN 492-39-7) ; Chlorine (CAS RN 7782-50-5) ; Chloroacetic acid (CAS RN 79-11-8) ; Chloroform (CAS RN 67-66-3) ; Chlorpropham (CAS RN 101-21-3) ; Chlorpyrifos (CAS RN 2921-88-2) ; Chromic trioxide (CAS RN 1333-82-0) ; Chromium (CAS RN 7440-47-3) ; Chromium(6+) (CAS RN 18540-29-9) ; Chrysene (CAS RN 218-01-9) ; Chrysotile (CAS RN 12001-29-5) ; Cinerin I (CAS RN 25402-06-6) ; Cinerin II (CAS RN 121-20-0) ; cis-Mevinphos (CAS RN 298-01-1) ; Cobalt (CAS RN 7440-48-4) ; Copper (CAS RN 7440-50-8) ; Cristobalite (CAS RN 14464-46-1) ; Crocidolite asbestos (CAS RN 12001-28-4) ; Cyclohexanone (CAS RN 108-94-1) ; Cyclopentanone (CAS RN 120-92-3) ; Cyclophosphamide (CAS RN 50-18-0) ; Cyhexatin (CAS RN 13121-70-5) ; D-Amphetamine (CAS RN 51-64-9) ; D-Amphetamine sulfate (CAS RN 51-63-8) ; Diazinon (CAS RN 333-41-5) ; Dibenz[a, h]anthracene (CAS RN 53-70-3) ; Dichloromethane (CAS RN 75-09-2) ; Dicrotophos (CAS RN 141-66-2) ; Dimethyl (1Z)-1-methyl-3-(methylamino)-3-oxo-1-propen-1-yl phosphate (CAS RN 919-44-8) ; Dimethylarsinic acid (CAS RN 75-60-5) ; Dimethyltin dichloride (CAS RN 753-73-1) ; Disulfoton (CAS RN 298-04-4) ; Diuron (CAS RN 330-54-1) ; DL-Ephedrine (CAS RN 90-81-3) ; DL-Ephedrine hydrochloride (CAS RN 134-71-4) ; Ephedrine (CAS RN 299-42-3) ; Ethanol (CAS RN 64-17-5) ; Ethion (CAS RN 563-12-2) ; Ethoprophos (CAS RN 13194-48-4) ; Ethylbenzene (CAS RN 100-41-4) ; Ethylene oxide (CAS RN 75-21-8) ; Fenamiphos (CAS RN 22224-92-6) ; Fenchlorphos (CAS RN 299-84-3) ; Ferro-actinolite (CAS RN 15669-07-5) ; Fluoranthene (CAS RN 206-44-0) ; Fluorene (CAS RN 86-73-7) ; Fluoride (CAS RN 16984-48-8) ; Fonofos (CAS RN 944-22-9) ; Formaldehyde (CAS RN 50-00-0) ; Formetanate hydrochloride (CAS RN 23422-53-9) ; Glutaraldehyde (CAS RN 111-30-8) ; Hexane (CAS RN 110-54-3) ; Hydrochloric acid (CAS RN 7647-01-0) ; Hydrofluoric acid (CAS RN 7664-39-3) ; Hydrogen bromide (CAS RN 10035-10-6) ; Hydrogen cyanide (CAS RN 74-90-8) ; Hydroquinone (CAS RN 123-31-9) ; Ifosfamide (CAS RN 3778-73-2) ; Indeno[1,2,3-cd]pyrene (CAS RN 193-39-5) ; Indium (CAS RN 7440-74-6) ; Iron (CAS RN 7439-89-6) ; Isobutyl ketone (CAS RN 108-83-8) ; Isopropanol (CAS RN 67-63-0) ; Jasmolin I (CAS RN 4466-14-2) ; Jasmolin II (CAS RN 1172-63-0) ; Lanthanum (CAS RN 7439-91-0) ; Lead (CAS RN 7439-92-1) ; Lead oxide (PbO) (CAS RN 1317-36-8) ; Lithium (CAS RN 7439-93-2) ; Lithium hydroxide (CAS RN 1310-65-2) ; Lizardite (CAS RN 12161-84-1) ; Magnesium (CAS RN 7439-95-4) ; Malathion (CAS RN 121-75-5) ; Manganese (CAS RN 7439-96-5) ; Methamidophos (CAS RN 10265-92-6) ; Methamphetamine (CAS RN 537-46-2) ; Methanol (CAS RN 67-56-1) ; Methiocarb (CAS RN 2032-65-7) ; Methomyl (CAS RN 16752-77-5) ; Methyl bromide (CAS RN 74-83-9) ; Methyl ethyl ketone (CAS RN 78-93-3) ; Methyl isobutyl ketone (CAS RN 108-10-1) ; Methylarsonic acid (CAS RN 124-58-3) ; Methylenedioxyethylamphetamine (CAS RN 82801-81-8) ; Methyltin trichloride (CAS RN 993-16-8) ; Mevinphos (CAS RN 7786-34-7) ; Mitomycin C (CAS RN 50-07-7) ; Molybdenum (CAS RN 7439-98-7) ; Monocrotophos (CAS RN 6923-22-4) ; m-Xylene (CAS RN 108-38-3) ; N-Acetyl-S-phenylcysteine (CAS RN 20640-68-0) ; Naphthalene (CAS RN 91-20-3) ; Nickel (CAS RN 7440-02-0) ; Nitric acid (CAS RN 7697-37-2) ; Nitrobenzene (CAS RN 98-95-3) ; Nitrous oxide (CAS RN 10024-97-2) ; Norpseudoephedrine (CAS RN 36393-56-3) ; Norpseudoephedrine, hydrochloride (CAS RN 2153-98-2) ; o-Cresol (CAS RN 95-48-7) ; Oxamyl (CAS RN 23135-22-0) ; o-Xylene (CAS RN 95-47-6) ; Parathion (CAS RN 56-38-2) ; Parathion-methyl (CAS RN 298-00-0) ; Pentanal (CAS RN 110-62-3) ; Phenanthrene (CAS RN 85-01-8) ; Phencyclidine (CAS RN 77-10-1) ; Phencyclidine hydrochloride (CAS RN 956-90-1) ; Phentermine (CAS RN 122-09-8) ; Phentermine hydrochloride (CAS RN 1197-21-3) ; Phenylpropanolamine hydrochloride (CAS RN 154-41-6) ; Phorate (CAS RN 298-02-2) ; Phosphine (PH3) (CAS RN 7803-51-2) ; Phosphoric acid (CAS RN 7664-38-2) ; Phosphorus (CAS RN 7723-14-0) ; Platinum (CAS RN 7440-06-4) ; Potassium (CAS RN 7440-09-7) ; Potassium hydroxide (CAS RN 1310-58-3) ; Propham (CAS RN 122-42-9) ; Propoxur (CAS RN 114-26-1) ; Pseudoephedrine (CAS RN 90-82-4) ; Pseudoephedrine hydrochloride (CAS RN 345-78-8) ; p-Xylene (CAS RN 106-42-3) ; Pyrene (CAS RN 129-00-0) ; Pyrethrin I (CAS RN 121-21-1) ; Pyrethrin II (CAS RN 121-29-9) ; Pyrethrins (CAS RN 8003-34-7) ; Quartz (SiO2) (CAS RN 14808-60-7) ; Refractories, fibers, aluminosilicate (CAS RN 142844-00-6) ; Rotenone (CAS RN 83-79-4) ; Selenium (CAS RN 7782-49-2) ; Serpentine-group minerals (CAS RN 12168-92-2) ; Silver (CAS RN 7440-22-4) ; Sodium (CAS RN 7440-23-5) ; Sodium hydroxide (CAS RN 1310-73-2) ; Strontium (CAS RN 7440-24-6) ; Strychnine (CAS RN 57-24-9) ; Styrene (CAS RN 100-42-5) ; Sulfonyl fluoride (CAS RN 2699-79-8) ; Sulfur dioxide (CAS RN 7446-09-5) ; Sulfuric acid (CAS RN 7664-93-9) ; Sulprofos (CAS RN 35400-43-2) ; Tellurium (CAS RN 13494-80-9) ; Terbufos (CAS RN 13071-79-9) ; Tetrabutyltin (CAS RN 1461-25-2) ; Tetrafluoroethylene (CAS RN 116-14-3) ; Tetrahydrofuran (CAS RN 109-99-9) ; Tetramethylthiuram disulfide (CAS RN 137-26-8) ; Thallium (CAS RN 7440-28-0) ; Thiobencarb (CAS RN 28249-77-6) ; Tin (CAS RN 7440-31-5) ; Titanium (CAS RN 7440-32-6) ; Toluene (CAS RN 108-88-3) ; Tremolite asbestos (CAS RN 77536-68-6) ; Tributyltin chloride (CAS RN 1461-22-9) ; Trichloroacetic acid (CAS RN 76-03-9) ; Trichloroethylene (CAS RN 79-01-6) ; Tridymite (SiO2) (CAS RN 15468-32-3) ; Trimethyltin chloride (CAS RN 1066-45-1) ; Tungsten (CAS RN 7440-33-7) ; Vanadium (CAS RN 7440-62-2) ; Vinyl acetate (CAS RN 108-05-4) ; Vinylidene fluoride (CAS RN 75-38-7) ; Yttrium (CAS RN 7440-65-5) ; Zinc (CAS RN 7440-66-6) ; Zinc oxide (ZnO) (CAS RN 1314-13-2) ; Zirconium (CAS RN 7440-67-7)
• Editor(s):
  Andrews, Ronnee ; O'Connor, Paula Fey ; Ashley, Kevin E.
• Federal Fiscal Year:
  2020
• Peer Reviewed:
  False
• Collection(s):
  National Institute for Occupational Safety and Health
• Main Document Checksum:
  urn:sha-512:96366f259b24d1d927b90c0b4eace101eb54caab69118db87bf6e67f6d97f1d06833a03df4a4a3ce648f83d7c50317aac797651614938260227ed4f0015ddd47
• Download URL:
  https://stacks.cdc.gov/view/cdc/103173/cdc_103173_DS1.pdf
• File Type:
  [PDF - 16.23 MB ]