Aerosol Analysis Using Quantum Cascade Laser Infrared Spectroscopy: Application to Crystalline Silica Measurement

Details

• Personal Author:
  Ashley, Kevin E. ; Kulkarni P ; Wei S ; Zheng L
• Description:
  A method for trace analysis of aerosol mineral components using quantum cascade laser (QCL) based infrared absorption spectroscopy is described. The measurement approach involves: (a) collection of aerosol on a particulate filter; (b) sample treatment using low-temperature oxygenated plasma to minimize the matrix interferences; (c) redeposition of the treated sample as a dried spot for direct-on-filter analysis; and (d) infrared transmittance measurement of the dried spot using the QCL and mercury-cadmium-telluride detector. The method was applied to quantification of trace a-quartz in workplace aerosols. Infrared absorbance spectra in the range 750-1030 cm-1 were obtained using the QCL instrument; the characteristic peak of a-quartz at 798 cm-1 was used to measure its content. A correction scheme was applied to account for spectral interference from kaolinite mineral for coal dust samples. The detection limit for a-quartz was estimated to be 0.12 µg for a dried spot diameter of 1 mm. This detection limit is an order-of-magnitude lower than those attainable by the current standard X-ray diffraction (XRD) or Fourier transform infrared spectroscopy (FTIR) methods involving similar sample preparation and treatment. The QCL method was extended to the measurement of respirable a-quartz concentrations in workplace aerosols released during cutting of fiber-reinforced cement and engineered stone products (used in building construction), as well as those from various coal mine dusts. The measurements compared well with those from the standard XRD method, even for samples with matrix and mineral interferences. The results show that QCL-based IR transmission spectroscopy can offer sensitive, trace-level measurement of aerosol mineral components. [Description provided by NIOSH]
• Subjects:
  Aerosols Dust Occupational Health Particulate Matter Quartz Safety Silicon Dioxide
• Keywords:
  Aerosol Sampling Analytical Instruments Author Keywords: Quantum Cascade Laser Coal Dust Crystalline Silica Crystalline Silica Aerosol Filters Infrared Spectroscopy Particulates Respirable Dust Sample Preparation Spectroscopes Trace Analysis

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• ISSN:
  0021-8502
• Document Type:
  Text
• Genre:
  Journal Article
• Place as Subject:
  Arizona ; Ohio ; OSHA Region 5 ; OSHA Region 9
• CIO:
  National Institute for Occupational Safety and Health (NIOSH)
• Division:
  HELD - Health Effects Laboratory Division
• Topic:
  Workplace Safety & Health
• Location:
  North America
• Volume:
  150
• NIOSHTIC Number:
  nn:20060833
• Citation:
  J Aerosol Sci 2020 Dec; 150:105643
• Contact Point Address:
  Pramod Kulkarni, Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health, 1090 Tusculum Avenue, Cincinnati, OH 45226, USA
• Email:
  PSKulkarni@cdc.gov
• CAS Registry Number:
  Quartz (SiO2) (CAS RN 14808-60-7)
• Federal Fiscal Year:
  2021
• NORA Priority Area:
  Oil and Gas Extraction
• Peer Reviewed:
  True
• Source Full Name:
  Journal of Aerosol Science
• Collection(s):
  National Institute for Occupational Safety and Health
• Main Document Checksum:
  urn:sha-512:1502dad9ef7a746c46f3978dc98a1100889a0b1717f0ca731616b44ac1fdf54979d58e9e13cd61c314cb0e175b0fad72a816da684e74804e6bcaee15ef72e744
• Download URL:
  https://stacks.cdc.gov/view/cdc/224630/cdc_224630_DS1.pdf
• File Type:
  [PDF - 6.33 MB ]