Catalytic Reduction of Sulfur Dioxide on Iron-Alumina Bifunctional Catalysts
Public Domain
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1971/06/01
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Series: Mining Publications
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Description:Mixtures of alumina and iron powder provide efficient catalysts for the interaction of low concentration of so2 with carbon monoxide The catalytic reaction rate at 500 deg. C depended significantly on the iron content of the binary catalyst mixture. Mixtures containing 43 percent freshly reduced iron exhibited a sharp peak in the catalytic activity at 500 deg. C when compared with other catalyst compositions. The normalized reaction rate per gram of iron, instead of per gram of total catalyst, still portrayed a sharp maximum when plotted against the weight fraction of iron in the catalyst. This fact, in addition to nonsynergistic effects observed with iron-silica mixtures, disqualifies interpretations based solely on the antisintering or supportive action of alumina on iron. The results are best explained on the basis of a dual reaction site mechanism with both iron and alumina augmenting their specific sites activity at their interparticle contacts. [Description provided by NIOSH]
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Pages in Document:133-137
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Volume:10
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NIOSHTIC Number:nn:10010629
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Citation:I&ec Product Res and Dev 1971 Jun; 10:133-137
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Federal Fiscal Year:1971
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Peer Reviewed:False
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Source Full Name:I&ec Product Res. and Dev., V. 10, June 1971, PP. 133-137
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Main Document Checksum:urn:sha-512:5998e6e8b36a11067f5027696c4b8fd1d648f5230ece4f2f92fbf0a772c683edb4433161db80e9158985f8d34de0758875d2bf905b1c5619783f032855fa7261
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