Thermodynamic Properties of Acrylonitrile, 1-Aminopropane, 2- Aminopropane, and 2-Methyl-2-Aminopropane

Details

• Personal Author:
  Finke HL ; Messerly JF ; Todd SS
• Description:
  Low-temperature calorimetric quantities were determined for acrylonitrile, 1-aminopropane, 2-aminopropane, and 2-methyl-2- aminopropane from 12 deg k to near their respective normal boiling temperatures. Values of molar heat capacity at saturation pressure of the condensed phases, transition and melting temperatures, and enthalpies of transition and fusion were measured by adiabatic calorimetry. From these data the thermodynamic quantities - [g8(t) - h deg (0)]/t, [h8(t) - h deg (0)]/t, [h8(t) - h deg (0)], s8, and c8 were evaluated for the solid and liquid states. For acrylonitrile a revised vibrational assignment was made from raman and infrared wavenumbers reported in the literature, and a table of thermodynamic functions for the ideal gas state from 0 deg to 1,000 deg k was prepared. Values of the enthalpy, Gibbs energy, and logarithm of equilibrium constant of formation for acrylonitrile also were computed for the range 0 deg to 1,000 deg k. [Description provided by NIOSH]
• Subjects:
  Chemistry Occupational Health Safety
• Keywords:
  Analytical-processes Chemical-properties Chemical-reactions Thermodynamic-reactions Thermodynamics
• Series:
  Mining Publications
• ISSN:
  0021-9614
• Document Type:
  Text
• Genre:
  Journal Article
• Place as Subject:
  Oklahoma ; OSHA Region 6
• CIO:
  National Institute for Occupational Safety and Health (NIOSH)
• Division:
  BERC - Bartlesville Energy Research Center
• Topic:
  Workplace Safety & Health
• Location:
  North America
• Pages in Document:
  359-374
• Volume:
  4
• Issue:
  3
• NIOSHTIC Number:
  nn:10010418
• Citation:
  J Chem Thermodynamics 1972 May; 4(3):359-374
• CAS Registry Number:
  Acrylonitrile (CAS RN 107-13-1) ; Isopropylamine (CAS RN 75-31-0) ; Propylamine (CAS RN 107-10-8)
• Federal Fiscal Year:
  1972
• Peer Reviewed:
  False
• Source Full Name:
  The Journal of Chemical Thermodynamics
• Collection(s):
  National Institute for Occupational Safety and Health
• Main Document Checksum:
  urn:sha-512:664c6553d9dfbdc7c279743d621501ffdd231f8645358fffbc9d1af5d10a20cca31db7893e018f051b6614f87683ed6d3e03a582bc04ab15e9680a2ec650a7f9
• Download URL:
  https://stacks.cdc.gov/view/cdc/220013/cdc_220013_DS1.pdf
• File Type:
  [PDF - 920.05 KB ]