Change in Tensile Properties of Neoprene and Nitrile Gloves After Repeated Exposures to Acetone and Thermal Decontamination

Details

• Personal Author:
  Gao, Peng-Fei ; Tomasovic B
• Description:
  This study investigated the change in tensile properties of neoprene and nitrile gloves after repeated cycles of exposure to acetone, followed by thermal decontamination. The glove was exposed to acetone (outer surface in contact with chemical), subjected to thermal decontamination, and tested for the tensile strength and the ultimate elongation. Thermal decontamination was carried out inside an oven for 16 hours at 100 degrees C. The exposure/decontamination procedure was repeated for a maximum of 10 cycles. For neoprene versus acetone, the mean tensile strength consistently decreased after each exposure/decontamination cycle. Multiple comparisons indicated that the mean tensile strengths between the new swatches and each exposure/decontamination group were significantly different (p < 0.05). The loss of either tensile strength or ultimate elongation was less than 23% compared with new swatches after four exposure/decontamination cycles. Swatches with out acetone exposure were then cycled through the oven in the same manner. It was found that both the heat used for thermal decontamination and acetone exposure significantly affected the tensile strength and ultimate elongation. For nitrile gloves exposed to acetone, the mean tensile strength remained virtually unchanged (p > 0.05). The mean tensile strength for the new swatches was 37.1 MPa and the mean tensile strength after nine exposure/decontamination cycles was 36.0 MPa, with a loss less than 3%. The largest single cycle loss for ultimate elongation occurred during the first exposure/decontamination cycle for both glove materials. In our previous study, decisions regarding the effectiveness of the decontamination process were based on having no discernible change in the breakthrough time and steady-state permeation rate. The results of this study indicate that the effectiveness of the decontamination process cannot be based on permeation parameters alone but must also take into account the change in physical properties. [Description provided by NIOSH]
• Subjects:
  Acetone Environmental Monitoring Nitriles Occupational Health Personal Protective Equipment Safety
• Keywords:
  Acetones Exposure-assessment Exposure-levels Gloves Personal-protective-equipment Protective-equipment
• ISSN:
  1545-9624
• Document Type:
  Text
• Genre:
  Journal Article
• Place as Subject:
  OSHA Region 3 ; Pennsylvania
• CIO:
  National Institute for Occupational Safety and Health (NIOSH)
• Division:
  NPPTL - National Personal Protective Technology Laboratory
• Topic:
  Workplace Safety & Health
• Location:
  North America
• Volume:
  2
• Issue:
  11
• NIOSHTIC Number:
  nn:20028931
• Citation:
  J Occup Environ Hyg 2005 Nov; 2(11):543-552
• Email:
  pcg9@cdc.gov
• CAS Registry Number:
  Acetone (CAS RN 67-64-1) ; Polychloroprene (CAS RN 9010-98-4)
• Federal Fiscal Year:
  2006
• Peer Reviewed:
  True
• Source Full Name:
  Journal of Occupational and Environmental Hygiene
• Collection(s):
  National Institute for Occupational Safety and Health
• Main Document Checksum:
  urn:sha-512:1b4c4c8484994df44bc84abfd9a4a773fecdefc9dab5fcd68efcf002ede4b0b3e69572ed5c21a38859132ed39e9f7ea8f2ef889b360f785fb3866d0a1f4cbf93
• Download URL:
  https://stacks.cdc.gov/view/cdc/190019/cdc_190019_DS1.pdf
• File Type:
  [PDF - 1.54 MB ]