Control technology for furfuryl alcohol - based systems: the furan no-bake process.
Public Domain
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1981/08/01
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By Eftax DS
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Description:Control technology for the no bake chemically bonded sand process used to produce cores and molds at room temperature was reviewed. Recommended controls and precautions for improving the quality of the workplace environment during the use of the furan (110009) foundry binder system, which uses binders based on furfuryl-alcohol (98000), were outlined. Emphasis was given to precautionary measures, controls, and personal protection during mixing, molding, coremaking, pouring, cooling, and shakeout. Foundry measurements made in the mixing areas of 40 foundries pouring from 5 to more than 100 tons of ferrous metal per day revealed the presence of furfuryl- alcohol in amounts lower than 50 parts per million (ppm), while half the breathing zone measurements showed levels lower than 5ppm. Formaldehyde (50000) concentrations for furan binders formulated with it averaged 1ppm, while the levels of toluene (108883) and benzene (71432) in the air were about 1ppm each. The Occupational Safety and Health Administration permissible exposure limits for these compounds were 50ppm (furfuryl-alcohol), 3ppm (formaldehyde), 200ppm (toluene), and 10ppm (benzene). Depending on the specific formulation used, decomposition products of binder systems could include carbon-dioxide (124389), carbon-monoxide (630080), hydrocarbons, formaldehyde, ammonia (7664417), hydrogen-cyanide (74908), sulfur-dioxide (7446095), and hydrogen-sulfide (7783064). The author indicates that many of the recommended controls for the no bake process may be applicable to other processes, such as the hot box, cold box, and warm box processes.
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Pages in Document:137-141
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NIOSHTIC Number:nn:00175063
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Citation:Proceedings of the symposium on occupational health hazard control technology in the foundry and secondary non-ferrous smelting industries, December 10-12, 1979, Chicago, Illinois. Cincinnati, OH: U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control, National Institute for Occupational Safety and Health, DHHS (NIOSH) Publication No. 81-114, 1981 Aug; :137-141
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CAS Registry Number:Furan (CAS RN 110-00-9) ; Furfuryl alcohol (CAS RN 98-00-0) ; Formaldehyde (CAS RN 50-00-0) ; Toluene (CAS RN 108-88-3) ; Benzene (CAS RN 71-43-2) ; Carbon dioxide (CAS RN 124-38-9) ; Carbon monoxide (CAS RN 630-08-0) ; Ammonia (CAS RN 7664-41-7) ; Hydrogen cyanide (CAS RN 74-90-8) ; Sulfur dioxide (CAS RN 7446-09-5) ; Hydrogen sulfide (CAS RN 7783-06-4)
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Federal Fiscal Year:1981
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Peer Reviewed:False
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Source Full Name:Proceedings of the symposium on occupational health hazard control technology in the foundry and secondary non-ferrous smelting industries, December 10-12, 1979, Chicago, Illinois
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Main Document Checksum:urn:sha-512:848f30a96d99c74be09208ac3a1419c91c3cdec0fa84878e34cf734d215a70ccd31b44b769266cd1cadfbe61063e4cb89558f4296e839bf756956f193e31001a
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