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Further study of the intrinsic safety of internally shorted lithium and lithium-ion cells within methane-air

Filetype[PDF-1.66 MB]


  • English
    • Details Supporting Files You May Also Like

    Details:

    • Alternative Title:
      J Loss Prev Process Ind
    • Personal Author:
    • Description:
      National Institute for Occupational Safety and Health (NIOSH) researchers continue to study the potential for lithium and lithium-ion battery thermal runaway from an internal short circuit in equipment for use in underground coal mines. Researchers conducted cell crush tests using a plastic wedge within a 20-L explosion-containment chamber filled with 6.5% CH|-air to simulate the mining hazard. The present work extends earlier findings to include a study of LiFePO| cells crushed while under charge, prismatic form factor LiCoO| cells, primary spiral-wound constructed LiMnO| cells, and crush speed influence on thermal runaway susceptibility. The plastic wedge crush was a more severe test than the flat plate crush with a prismatic format cell. Test results indicate that prismatic Saft MP 174565 LiCoO| and primary spiral-wound Saft FRIWO M52EX LiMnO| cells pose a CH|-air ignition hazard from internal short circuit. Under specified test conditions, A123 systems ANR26650M1A LiFePO| cylindrical cells produced no chamber ignitions while under a charge of up to 5 A. Common spiral-wound cell separators are too thin to meet intrinsic safety standards provisions for distance through solid insulation, suggesting that a hard internal short circuit within these cells should be considered for intrinsic safety evaluation purposes, even as a non-countable fault. Observed flames from a LiMnO| spiral-wound cell after a chamber ignition within an inert atmosphere indicate a sustained exothermic reaction within the cell. The influence of crush speed on ignitions under specified test conditions was not statistically significant.
    • Subjects:
    • Source:
      J Loss Prev Process Ind. 32:165-173
    • Pubmed ID:
      26139958
    • Pubmed Central ID:
      PMC4485987
    • Document Type:
      Journal Article
    • Funding:
      CC999999/Intramural CDC HHSUnited States/
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